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Q.

A closed tank has two compartments A and B, both filled with oxygen (assumed to be ideal gas).The partition separating the two compartments is fixed and is a perfect heat insulator (Figure 1). If the old partition is replaced by a new partition which can slide and conduct heat but does NOT allow the gas to leak across (Figure 2), the volume (in m3) of the compartment A after the system attains equilibrium  is ______.

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answer is 2.22.

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Detailed Solution

P1=5                P2=1v1=1                   v2=3T1=400             T2=300n1=5400R        n2=3300RLet volume be(v+x)                      v=(3-x)                           15-5x=4+4xPATA=PBTB⇒nb×Rvb1=nb2×Rvb2⇒5400(4+x)=3300R(3−x)⇒5(3−x)=4+4x⇒x=119v=1+x=1+119=209=2.22
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