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Q.

A closed vessel with rigid walls contains 1 mol of  92238U  and 1 mol of air at 298K. Considering complete decay of  92238U to 82206Pb,  the ratio of the final pressure to the initial pressure of the system at 298K is

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answer is 9.

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Detailed Solution

Let us assume that          1 mol of air = X atm          During the reaction  92238U→82206Pb ,          8 ‘a’ particles released .          8 moles of ‘He’ particles released during the reaction.          \ 9 moles of gas released during reaction.          \Total pressure = 9 atm          = 9 times of original pressure
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