15 cm3 of liquid 'x' and 20 cm3 of liquid 'y' are mixed at 20ºC and the volume of solution was measured to be 35.1 cm3 then correct reaction is
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a
ΔHmix < 0, solution shows +ve deviation
b
ΔHmix > 0, solution shows +ve deviation
c
ΔHmix < 0, solution shows –ve deviation
d
ΔHmix > 0, solution shows –ve deviation
answer is B.
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Detailed Solution
given Vmix= 35.1ccVA=15 , VB=20cc Vmix.is greater than expected , so It is a non ideal solution(acc. to Raoult's law)Hence(1) It shows positive deveation(2) Heat is absorbed, (3) Vapour pressure will be more than ideal solution