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Q.

15 cm3 of liquid 'x' and 20 cm3 of liquid 'y' are mixed at 20ºC and the volume of solution was measured to be 35.1 cm3 then correct reaction is

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a

ΔHmix < 0, solution shows +ve deviation

b

ΔHmix > 0, solution shows +ve deviation

c

ΔHmix < 0, solution shows –ve deviation

d

ΔHmix > 0, solution shows –ve deviation

answer is B.

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Detailed Solution

given    Vmix= 35.1ccVA=15  ,   VB=20cc Vmix.is greater than expected , so It is a non ideal solution(acc. to Raoult's law)Hence(1)         It shows positive deveation(2) Heat is absorbed,   (3) Vapour pressure will be more than ideal solution
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