Q.
For CO, isotherm is of the type as shown. Near the point A, compressibility factor Z is
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a
1+bV
b
1−bV
c
1+aRTV
d
1−aRTV
answer is D.
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Detailed Solution
At point A near low pressure region, volume is very high thus, (V - b) ≈ V∴ p+aV2V=RT⇒ pV+aV=RT⇒ Z=PVRT=1−aRTV
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