For CO, isotherm is of the type as shown. Near the point A, compressibility factor Z is

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1+bV

1−bV

1+aRTV

1−aRTV

answer is D.

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Detailed Solution

At point A near low pressure region, volume is very high thus, (V - b) ≈ V∴ p+aV2V=RT⇒ pV+aV=RT⇒ Z=PVRT=1−aRTV

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