First slide

Structural isomerism

Question

$[Co {({NH}_{3})}_{5} Br] {SO}_{4}$ and $[Co {({NH}_{3})}_{5} {SO}_{4}] Br$ are the examples of:

Easy

A

linkage isomerism
B

geometrical isomerism
C

optical isomerism
D

ionization isomerism

Solution

Both produce different ions in solution state:
$\begin{array}{l} [Co {({NH}_{3})}_{5} Br] {SO}_{4} ⇌ {[Co {({NH}_{3})}_{5} Br]}^{2 +} + {SO}_{4}^{2 -} \\ [Co {({NH}_{3})}_{5} {SO}_{4}] Br ⇌ {[Co {({NH}_{3})}_{5} {SO}_{4}]}^{+} + {Br}^{-} \end{array}$

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