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Q.

CoNH34NO22Cl exhibits

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a

linkage isomerism, ionization isomerism and geometrical isomerism

b

ionization isomerism, geometrical isomerism and optical isomerism

c

linkage isomerism, geometrical isomerism and optical isomerism

d

linkage isomerism, ionization isomerism and optical isomerism

answer is A.

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Detailed Solution

The given compound may have linkage isomerism due to presence of NO2  group which may be in the form -NO2  or ONO .It may have ionisation isomerism due to presence of two ionisable group -NO2 & -CI . It may have geometrical isomerism in the form of cis-trans form as followsCo(NH3)4CI(NO2)NO2&Co(NH3)4(NO2)2CI - ionisation isomersCo(NH3)5(NO2)CI&Co(NH3)5(ONO)CI -   Linkage isomers
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