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Derivatives of carbonyl compounds

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By Expert Faculty of Sri Chaitanya
Question

COLUMN - I

Reaction

COLUMN - II

Product

a.(COOH)22H2OΔ105C (I) p.2CO2+H2O
b. (I) Δ at 200C or H2SO4, at 90Cq.(COOH)2
c.
r.CO+CO2+H2O
d. (I) ΔKMnO4s.Carbon suboxide (O=C=C=C=O)
e.2HCOONaΔ,360CH3Ot.MeCOOH+CO2
f.
  

Difficult
Solution

(aq) Oxalic acid dihydrate loses H,O when heated  at 105°C.

(br) When heated at 200°C or when refluxed with H2SO4 at 90°C, it decomposes into CO2,CO,HCOOH, and H2O.(COOH)2CO2+HCOOHCO+H2O

(cs) Malonic acid on heating with P2O5 loses H2O and forms carbon suboxide.

(dq) Oxalic acid is oxidised by KMnO4 to CO2 (COOH)2 to [O] 2CO2 + H2O)

(eq) It is the industrial method fo the preparation of oxalic acid.

(ft) Malonic acid under these conditions given MeCOOH + CO2.


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