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Q.

Complex compound Cr(NCS)NH35ZnCl4 will be :

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a

colourless and diamagnetic

b

green coloured and diamagnetic

c

green coloured and shows coordination isomerism

d

diamagnetic and shows linkage isomerism

answer is C.

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Detailed Solution

Due to the cationic part of the complex, it is green, because there are three unpaired electrons in t2g orbitals of Cr3+ cation, both cationic and anionic pans are complex ions, hence, coordination isomerism will be exhibited by it.
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Complex compound Cr(NCS)NH35ZnCl4 will be :