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Q.

The complex ion Fe(CN)64− contains:

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a

total of 36 electrons on Fe2+ cation

b

sp3d2 hybrid orbitals with octahedral structure

c

total of 104 electrons

d

six sigma bonds

answer is A.

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Detailed Solution

Fe(CN)64− contains total of 36 electrons on Fe2+ cation.  EAN =Z− O. S. +2× C.N. =26−2+2×6=24+12→36d2sp3 hybridisation; total of 108 electrons and 12 sigma bonds.
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