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A compound (A) , C4H8Cl2 , on hydrolysis gives a product (B) which forms a 2,4-DNP derivative but does not reduce Tollens reagent . The compound (A) has the structure

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a

CH3CH2CHClCH2Cl

b

CH3CH2CCl2CH3

c

CH3CH2CH2CHCl2

d

CH3CHClCHClCH3

answer is B.

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Detailed Solution

Ketone group forms 2,4-DNP derivative but do not reduces Tollens reagent. Hence A must be non-terminal geminal dichlorideCH3CH2C(Cl)2CH

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