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Q.

A compound exists in the gaseous state both as monomer A and Dimer A2. The molecular weight of monomer is 48. In an exiperiment 96g of the compound has present in a vessel of 33.6 L and heated to 2730C . Calculate pressure developed if the compound exsits as a dimer to the extend of 50% by weight in atmosphere.

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answer is 2.

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Detailed Solution

Total moles of dimer and monomer in the mixture is 4896+4848=1.5 Then P=nRTV 1.5×22.4×546273×33.6 ⇒2
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A compound exists in the gaseous state both as monomer A and Dimer A2. The molecular weight of monomer is 48. In an exiperiment 96g of the compound has present in a vessel of 33.6 L and heated to 2730C . Calculate pressure developed if the compound exsits as a dimer to the extend of 50% by weight in atmosphere.