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Q.

A compound has the empirical formula CoCl3.5NH3. When an aqueous solution of this compound ii mixed with excess silver nitrate, 2 mol of AgCl precipitates per mol of compound. On reaction with excess HCl, no NH4+ is detected. Hence it is

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a

CoNH35Cl2Cl

b

CoNH35ClCl2

c

CoNH35Cl3

d

CoNH34Cl2Cl.NH3

answer is B.

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Detailed Solution

CoNH35ClCl2+Excess AgNO3→2AgCl        ↓Two chloride ions are present out of coordination sphere which is ionisable.
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