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A compound has the empirical formula CoCl3.5NH3. When an aqueous solution of this compound ii mixed with excess silver nitrate, 2 mol of AgCl precipitates per mol of compound. On reaction with excess HCl, no NH4+ is detected. Hence it is

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By Expert Faculty of Sri Chaitanya
a
CoNH35Cl2Cl
b
CoNH35ClCl2
c
CoNH35Cl3
d
CoNH34Cl2Cl.NH3

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detailed solution

Correct option is B

CoNH35ClCl2+Excess AgNO3→2AgCl        ↓Two chloride ions are present out of coordination sphere which is ionisable.


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