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Q.

Compound A releases an inert gas with HNO2 form isocyanate with HgCl2/CS2 and a solid with diethyl oxalate. It can be

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a

an optically active compound containing three C-atoms

b

a compound formed by the reduction product of reaction of AgCN (alc) with RCl.

c

a compound having – NH2 group at carbonyl carbon.

d

a compound which is formed by acylazide in alkaline medium.

answer is C.

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Detailed Solution

1o amines gives N2 (inert gas) with HNO2 and forms isocyanate with HgCl2/CS2 and a solid (N, N)-dialkyl oxamide) with diethyl oxalate.Thus, it can be(1) (2) (3)
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