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Q.

The compound (SiH3)3N  is expected to be:

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a

Pyramidal and more basic than (CH3)3N

b

Planar and less basic than (CH3)3N

c

Pyramidal and less basic than (CH3)3N

d

Planar and more basic than (CH3)3N

answer is B.

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Detailed Solution

(SiH3)3N  is planar and less basic than (CH3)3N  because lone pair of N atom is used to form dπ−pπ  back bonding with Si-atom.
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