Q.

Compound A undergoes tetramerisation in the given solvent. The van't Hoff factor is

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a

2.0

b

0.5

c

0.25

d

0.125

answer is C.

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Detailed Solution

4A1-α  ⇌  A4α/4            i=1-α+α41=1-34αα=degree of association = 1, i.e. 100% association                     i=1-34=0.25
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Compound A undergoes tetramerisation in the given solvent. The van't Hoff factor is