Q.

Compressibility factor for CO2 at 400 K and 71.0 bars is 0.8697. Molar volume of CO2 under these conditions is

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a

22.4 L

b

2.24 L

c

0.41 L

d

19. 5 L

answer is C.

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Detailed Solution

Z=pVnRT=0.8697 ∴ Vm=0.8697×nRTp=0.8697×1×0.083×40071 =0.41LR=0.083bar dm3K−1mol−1
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Compressibility factor for CO2 at 400 K and 71.0 bars is 0.8697. Molar volume of CO2 under these conditions is