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Q.

The compressibility factor for a real gas at high pressure is

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a

1+RT/pb

b

1

c

1+pb/RT

d

1−pb/RT

answer is C.

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Detailed Solution

P+aV2(V−b)=RTAt high pressure aV2 can be neglected PV−Pb=RT⇒PV=RT+PbPVRT=1+PbRT⇒Z=1+PbRT; Z>1 at high pressure

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The compressibility factor for a real gas at high pressure is