Q.

Conductometric titration curve of a equimolar mixture of a HCI and HCN with NaOH (ag) is :

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a

b

c

d

answer is D.

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Detailed Solution

Molar conductivity of H+ and OH are very high as compare to other ions. Initially conductance of solution sharply decreases due to consumption of free H+ then increases due to formation of salt (NaCN) and After complete neutralization further sharply increases due to presence of OH-.
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Conductometric titration curve of a equimolar mixture of a HCI and HCN with NaOH (ag) is :