Q.
Consider the acidity of the carboxylic acids:(1) PhCOOH(2) o−NO2C6H4COOH(3) p−NO2C6H4COOH(4) m−NO2C6H4COOHWhich of the following order is correct?
see full answer
Talk to JEE/NEET 2025 Toppers - Learn What Actually Works!
Real Strategies. Real People. Real Success Stories - Just 1 call away
An Intiative by Sri Chaitanya
a
2 > 3 > 4 > 1
b
2 > 4 > 3 > 1
c
2 > 4 > 1 > 3
d
1 > 2 > 3 > 4
answer is A.
(Unlock A.I Detailed Solution for FREE)
Ready to Test Your Skills?
Check your Performance Today with our Free Mock Test used by Toppers!
Take Free Test
Detailed Solution
Electron withdrawing group increases the acidic nature of benzoic acid, o-isomer will have higher acidic nature than -p position have more pronounce electron-withdrawing effect than NO2 group at -m position.Hence the order of acidity is 2 > 3 > 4 > 1