Consider that a d6 metal ion M2+ forms a complex with aqua ligands, and the spin only magnetic moment of the complex is 4.90BM. The geometry and the crystal field stabilization energy of the complex is?
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a
tetrahedral and−1.6Δt+1P
b
octahedral and −24Δ0+2P
c
tetrahedral and −0.6Δt
d
octahedral and −1.6Δ0
answer is C.
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Detailed Solution
The metal ion M2+ with d6 configuration with aqua ligands will have t2g4eg2 in octahedral field and eg3t2g3 in tetrahedral. Then crystal field stabilization energy in octahedral field will be −0.4×4+0.6×2+PΔ0 and in tetrahedral field−0.6×3+(0.4×3)+PΔt. The tetrahedral value is −0.6Δt+p; the value match with 3