Consider the following complexes
I) CoNH36+3
II) CoH2O6+3
III) CoCN6-3
the increasing order of wavelength of light absorbed is
II, I, III
I, II, III
III, II, I
III, I, II
Energy(or frequency) of light absorbed ∝ field strength of ligand; Wavelength of light absorbed ∝1field strength of ligand; Field strength of CN->NH3>H2O ∴Order of wavelength absorbed : III<I<II ;