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Q.

Consider the following complexesI) CoNH36+3II) CoH2O6+3III) CoCN6-3the increasing order of wavelength of light absorbed is

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a

II, I, III

b

I, II, III

c

III, II, I

d

III, I, II

answer is D.

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Detailed Solution

Energy(or frequency) of light absorbed ∝ field strength of ligand; Wavelength of light absorbed ∝1field strength of ligand; Field strength of CN->NH3>H2O ∴Order of  wavelength absorbed : III
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