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Q.

Consider the following Eo values. EFe3+/Fe2+o=+0.77V,ESn2+/Sno=−0.14V. The Ecello for the reaction; Sn(s)+2Fe(aq)3+→2Fe(aq)2++Sn(aq)2+ is:

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a

0.63 V

b

1.40 V

c

0.91 V

d

1.68 V

answer is C.

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Detailed Solution

Ecello=EOPSn/Sn2+o+ERPFe3+/Fe2+o            =0.14+0.77=0.91 V
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