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Q.

Consider the following gaseous equilibria given below: (I) N2+3H2⇌2NH3; Eqm. Constant =K1  (II) N2+O2⇌2NO;   Eqm. Constant =K2  (III) H2+12O2⇌H2O; Eqm. Constant =K3The equilibrium constant for the reaction,2NH3+52O2⇌2NO+3H2O  in terms of K1,K2 and K3   will be

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a

K1K2K3

b

K1K2K3

c

K1K32K2

d

K2K33K1

answer is D.

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Detailed Solution

Given, (I) N2+3H2⇌2NH3; Eqm. Constant =K1  (II) N2+O2⇌2NO;   Eqm. Constant =K2  (III) H2+12O2⇌H2O; Eqm. Constant =K3  2NH3+52O2⇌2NO+3H2O,K4=?---(IV) (IV)=1(I)+(II)+3(III) ∴K4=1K1×K2×K33
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