Consider the following perhalate ions in acidic mediumClO4−(I),BrO4−(II),IO4−(III)Arrange these in the decreasing order of oxidizing power
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a
I > II > III
b
I > III > II
c
II > I > III
d
II > III > I
answer is D.
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Detailed Solution
Standard reduction potential (in volts) of the perhalate ions are given as below. ClO4−+2H++2e−→ClO3−+H2OEo=+1.19 VBrO4−+2H++2e−→BrO3−+H2OEo=+1.74 VIO4−+2H++2e−→IO3−+H2OEo=+1.65 VMore the standard reduction potential more is tendency of perhalate ion to undergo reduction and more stronger it will be as an oxidising agent.