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Q.

Consider the following reactions, O3⇌O2+O           (fast        .....(i)O+O3⟶2O2        (slow)      .......(ii) The rate law expression should be

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a

r=kO32O2−1

b

r=kO3O2

c

r=kO32

d

r=kO2−1

answer is A.

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Detailed Solution

From Eq. (i) Keq =O2[O]O3or                [O]=KeqO3O2From Eq.(ii)  rate law =kO3[O]or                            r=kO3O3O2Keqor                          r=k′O32O2−1k′=k×Keq
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Consider the following reactions, O3⇌O2+O           (fast        .....(i)O+O3⟶2O2        (slow)      .......(ii) The rate law expression should be