Questions  

Consider the following reactions, 
O3O2+O           (fast        .....(i)O+O32O2        (slow)      .......(ii) 
The rate law expression should be

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By Expert Faculty of Sri Chaitanya
ctaimg
a
r=kO32O2−1
b
r=kO3O2
c
r=kO32
d
r=kO2−1
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detailed solution

Correct option is A

From Eq. (i) Keq =O2[O]O3or                [O]=KeqO3O2From Eq.(ii)  rate law =kO3[O]or                            r=kO3O3O2Keqor                          r=k′O32O2−1k′=k×Keq


ctaimg

Similar Questions

Following data is given for the reaction,X+YP

Experiment[X] mol L1[Y] mol L1Initial rate mol L1s1
I2.5×10-46×10-55×10-4
II5×10-412×10-54×10-3
III1×10-312×10-51.6×10-2

The order of reaction with respect to X and Y respectively are

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