Consider the following reactions. Primary alcohol is not the product in
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a
CH3-CH2-CH=CH2→b)H2O2/OH-a)B2H6/THF
b
HCHO→b)H2Oa)CH3MgBr
c
CH32C=CH2→b)H2Oa)conc.H2SO4
d
CH32CH-CHO→PtH2
answer is C.
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Detailed Solution
(1)…Hydro boration oxidation….Anti markonikov's addition of water….butan-1-ol(primary);(2)…RMgX with HCHO followed by hydrolysis…always primary alcohol….ethanol;(3)…Acidic hydration…Markonikov's addition of water…2-methyl-propan-2-ol(tertiary);(4)…RCHO on catalytic reduction…always primary alcohol….2-methyl-propan-1-ol ;