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Questions  

Consider the following statement.
I. When O2 is converted into O22+ bond order decreases.
II. O2 molecule is paramagnetic because it contains two unpaired electrons in π*2px and π*2py molecular orbitals.
III. The bond length in NO is greater than NO+.
Choose the correct option.

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By Expert Faculty of Sri Chaitanya
a
Only I
b
I and II
c
II and III
d
II and IV

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detailed solution

Correct option is C

Statement II and III are correct.The molecular orbital configuration of O2  molecule is as follows:   σ   1s2,   σ   *1s2,   σ   2s2,    σ   *2s2,   σ   2p2z,π2px2    =π2py2      ,π*2px1=π*2py1There are 10 bonding and 6 nonbonding electrons in the orbitals according to the molecular orbital configuration.Therefore,  Bond order =12[Bonding-antibonding]= 12[10−6]=12(4)=2Thus, the bond order O2 is 2. The molecular orbital configuration of O2+2 is σ1s2,σ*1s2,σ2s2,σ*2s2,σ2pz2,π2px2=π2py2There are 10 bonding  and 4 nonbonding electrons in the orbitals according to the molecular orbital configuration.Therefore, Bond order =12[Bonding-antibonding]=12[10−4]=3.Hence statement I is incorrect.
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Similar Questions

The increasing order of energies of various molecular orbitals are

 I. σ1s<σ*1s<σ2s<σ*2s<σ2pz<π2px=π2py<π*2px=π*2py<σ*2pz

 II. σ1s<σ*1s<σ2s<σ*2s<π2px=π2py<σ2pz<π*2px=π*2py<σ*2pz

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