Q.

Consider the following statements.I. In general, the temperature dependence of the equilibrium constant depends on the sign of ∆H for the reaction.II. The equilibrium constant for an exothermic reaction (negative, ∆H)decreases as the temperature increases.III. The equilibrium constant for an endothermic reaction (positive,∆H)increases as the temperature increases.IV. Temperature changes affect the equilibrium constant and rates of reactions.Choose the correct statements.

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a

I and II

b

III and IV

c

I, II and III

d

I, II, III and IV

answer is D.

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Detailed Solution

(i) In general, the temperature dependence of the equilibrium constant depends on the sign of ∆H for the reaction.(ii) The equilibrium constant for an exothermic reaction (negative ∆H) decreases as the temperature increases.(iii) The equilibrium constant for an endothermic reaction (positive ∆H) increases as the temperature increases.(iv) Temperature changes affect the equilibrium constant and rates of reaction.
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