Consider the four sulphate FeSO4, MnSO4, CoSO4 and ZnSO4. Four separate capsules of these materials have been made containing 0.1 mole of the substance and are suspended by a thread. Then a strong magnet is brought close to each capsule, Order of sulphates according to the strength of the response that the magnet will produce on these capsules is
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a
MnSO4>FeSO4>CoSO4>ZnSO4
b
FeSO4>MnSO4>CoSO4>ZnSO4
c
CoSO4>ZnSO4>FeSO4>MnSO4
d
CoSO4>FeSO4>MnSO4>ZnSO4
answer is A.
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Detailed Solution
The substance which have unpaired electron shows paramagnetic behaviour. The number of unpaired electrons present in these substances as follows :d5Mn2+=5 unpaired e−;d6Fe2+=4 unpaired e− (d 7 ) Co2+=3 unpaired e−;d10Zn= no unpaired