Consider the reaction:Cl2(aq)+H2S(aq)→S(s)+2H+(aq)+2Cl−(aq) The rate equation for this reaction is rate =k[Cl2][H2S] Which of these mechanisms is/are consistent with this rate equationA) Cl2+H2S→H++Cl−+Cl++HS−(slow) Cl++HS−→H++Cl−+S(fast)B) H2S⇔H++HS−(fast equilibrium) Cl2+HS−→2Cl−+H++S(slow)
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a
B only
b
Both A and B
c
Neither A nor B
d
A only
answer is D.
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Detailed Solution
Rate equation is to be derived wrt slow step ∴ From mechanism (A) Rate=k[Cl2[H2S]] Slow step is the rate determine step