Q.
Consider the reaction, Ethanal + Propanal →ΔOH−products. Product of the reaction cannot be
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a
CH3 – CH2 – CH = CH – CH2– CHO
b
CH3 – CH = CH – CHO
c
CH3 – CH2 – CH = C(CH3) – CHO
d
CH3 – CH2 – CH = CH – CHO
answer is A.
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Detailed Solution
This is an example of crossed aldol condensation between two aldehydes containing α-Hydrogen atoms.Possible Products :1. CH3−CH=O+H2CH−CHO→ΔOH−CH3−CH=CH−CHO+H2O2.3.4. CH3CH2−CH=O+H2CH−CHO→ΔOH−CH3−CH2−CH=CH−CHO 3 – Hexenal, CH3 – CH2 – CH = CH – CH2 – CHO can never be the product.
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