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Q.

Consider the reaction(i) PCl5(g)    ⇌   PCl3(g)   +  Cl2(g)(ii) N2O4  ⇌   2NO2(g)The addition of an inert gas at constant volume

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a

will increase the dissociation of PCl5 as well as N2O4

b

will reduce the dissociation of PCl5 as well as N2O4

c

will increase the dissociation of PCl5 and step up the formation of NO2

d

will not disturb the equilibrium of the reactions

answer is D.

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Detailed Solution

Since inert gas addition has no affect at constant volume.
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Consider the reaction(i) PCl5(g)    ⇌   PCl3(g)   +  Cl2(g)(ii) N2O4  ⇌   2NO2(g)The addition of an inert gas at constant volume