Consider the reaction, X→HgSO4, 60oCdil.H2SO4Ketone. The compound ‘X’ in this reaction can never be
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a
CH≡CH
b
CH3−C≡C−CH3
c
CH3−C≡CH
d
C6H5-C≡CH
answer is A.
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Detailed Solution
Acidic hydration of alkyne involves addition of water by Markonikoff's rule. The enol formed tautomerises to a stable ketone.∵Ethyne contains only two carbon atoms, the -OH group will be attached to terminal carbon atom.the enol formed tautomerises to an aldehyde.CH≡CH→dil.H2SO4CH|H=COH|H⇌tautomerismKeto-enolCH3-CH=O (2) . . . CH3-CO-CH2-CH3 is formed (3) . . . CH3-CO-CH3 is formed (4) . . . C6H5-CO-CH3 is formed