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Q.

ConsiderReaction-I; Gabriel phthalimide synthesisReaction-II; Hoffman's hypobromite reaction.Correct statement about these reactions is

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a

Both I and II are useful to prepare 10 aryl amine

b

I is useful to prepare 10 aryl amine but II cannot be used to prepare 10 aryl amine

c

II is useful to prepare 10 aryl amine but I cannot used to prepare 10 aryl amine

d

Both I and II are not useful to prepare 10 aryl amine

answer is C.

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Detailed Solution

I) The nucleophile formed isIt cannot react with C6H5-X to form C6H5-X; C6H5-X in non reactive towards nucleophilic substitution reactions due to resonance;Primary aryl amines cannot be prepared; II)Z-CONH2+Br2+4NaOH→Z−NH2+Na2CO3+2NaBr+H2O;Z  can  be   −Ror−C6H5;Any primary amine can be prepared;
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