Q.
ConsiderReaction-I; Gabriel phthalimide synthesisReaction-II; Hoffman's hypobromite reaction.Correct statement about these reactions is
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a
Both I and II are useful to prepare 10 aryl amine
b
I is useful to prepare 10 aryl amine but II cannot be used to prepare 10 aryl amine
c
II is useful to prepare 10 aryl amine but I cannot used to prepare 10 aryl amine
d
Both I and II are not useful to prepare 10 aryl amine
answer is C.
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Detailed Solution
I) The nucleophile formed isIt cannot react with C6H5-X to form C6H5-X; C6H5-X in non reactive towards nucleophilic substitution reactions due to resonance;Primary aryl amines cannot be prepared; II)Z-CONH2+Br2+4NaOH→Z−NH2+Na2CO3+2NaBr+H2O;Z can be −Ror−C6H5;Any primary amine can be prepared;
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