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Q.

Consider the reactions (i) 2CO(g)+2H2O(g)⇌2CO2(g)+2H2(g); Eqm. Constant =K1  (ii) CH4( g)+H2O(g)⇌CO(g)+3H2( g); Eqm. Constant =K2  (iii) CH4(g)+2H2O(g)⇌CO2(g)+4H2(g); Eqm. Constant =K3Which of the following relation is correct?

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a

K3=K1K2

b

K3=K12K22

c

K3=K1K2

d

K3=K1·K2

answer is D.

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Detailed Solution

CO(g)+H2O(g)⇌CO2(g)+H2(g);k1 CH4(g)+H2O(g)⇌CO(g)+3H2(g);K2 addition  CH4(g)+2H2O(g)⇌CO2(g)+4H2(g)k1·k2 ⇒ k3=k1·k2
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