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Q.

Consider the reversible reaction,  ABs ⇌ Ag + Bg ; Kp=81 atm2,   Equilibrium  pressure would be

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a

18 atm

b

9 atm

c

40.5 atm

d

27 atm

answer is A.

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Detailed Solution

Kp= pA.pB; Since equal moles of A and B are formed, XA=XB=12; pA=pB; 81 atm2=p2; p=9 atm; Ptot=9+9atm=18 atm;               or Kp=Ptot2Ptot2 ; Ptot=4KP Ptot=18 atm;
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