Q.

Consider the reversible reaction, PCl5g⇌PCl3g+Cl2g;  According to Lechatelier's principle,decomposition of  PCl5 is favoured  at

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a

High T, low  P

b

Low T, low P

c

Low T, high P

d

High T, high P

answer is A.

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Detailed Solution

It is an endothermic reaction, favoured at high temperature;∆ng=2-1=+1....positive ,  favoured at low  pressure
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Consider the reversible reaction, PCl5g⇌PCl3g+Cl2g;  According to Lechatelier's principle,decomposition of  PCl5 is favoured  at