Consider a titration of potassium dichromate solution with acidified Mohr's salt solution using diphenylamine as indicator. The number of moles of Mohr's salt required per mole of dichromate is
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a
3
b
4
c
5
d
6
answer is D.
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Detailed Solution
6Fe2++Cr2O72-+14H+⟶6Fe3++2Cr3++7H2O Cr2O72-⟶2Cr3+x-factor = 6 Mohr's salts FeSO4·NH42SO4·6H2O Oxidation, Fe2+⟶Fe3+x-factor = l mole ratio is reverse of x-factor ratio.Therefore, one mole of dichromate required = 6moles of Mohr's salt.