Consider the Vander Waals constants, a and b, for the following gases Gas Ar Ne Kr Xe a/(atm dm6mol−21.30.25.14.1b/10−2dm3mol−13.21.71.05.0Which gas is expected to have the highest critical temperature. Fill the atomic number of the gas as your answer
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answer is 36.
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Detailed Solution
Tc=8a27RbGreater value of ab⇒ higher is “TC”Gas a/bAr 1.33.2=0.406Ne 0.21.7=0.118Kr 5.11=5.1 Xe 4.15=0.82∴Tc has order : Kr>Xe>Ar>Ne