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Q.

Considering the following reaction, find the equivalent weight of chlorine, given that molar mass of Cl2 is M. Cl2+NaOH→NaCl+NaClO3+H2O

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a

5/3 M

b

3/5 M

c

M/3

d

2M/3

answer is B.

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Detailed Solution

Considering half oxidation and half reduction reaction: Oxidation: 6OH-+12Cl2→2ClO3-+3H2O+5e−Reduction: 52Cl2+5e−→5Cl−3 moles of Cl2 and 5 moles of electrons are involved in the redox reaction  equivalent  mass = molecularmass n factor =35M
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Considering the following reaction, find the equivalent weight of chlorine, given that molar mass of Cl2 is M. Cl2+NaOH→NaCl+NaClO3+H2O