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Q.

In conversation of limestone to lime,CaCO3(s)→CaO(s)+CO2(g)The values of ΔH∘ and ΔS∘ are +179.1kJmol−1 and 160.2 J/K respectively at 298 K and 1 bar. Assuming that ∆H°and ∆S° do not change with temperature above which conversation of limestone to lime will be spontaneous is:

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a

1008 K

b

1200 K

c

845 K

d

1118 K

answer is D.

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Detailed Solution

T=179.1×1000160.2=1118KSo, at the above temperature the reaction will become spontaneous.
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