Q.

For the conversion, RCN→RCH2NH2Select the correct option(s)

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a

It is an oxidation reaction

b

Reagents used in this reaction is LiAlH4,H2 / Ni.Na(Hg) /C2H5OH.

c

This reaction is used to decrease the number of C-atom

d

All of the above

answer is B.

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Detailed Solution

Nitriles on reduction with lithium aluminium hydride (LiAlH4) or catalytic hydrogenation produce primary amines. This reaction is used for preparation of amines containing one carbon atom more than the starting amine.
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