Q.

The conversion of vinyl allyl ether to pent-4-enol follows first order kinetics. The following plot is obtained for such a reaction:The rate constant for the reaction is

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a

Ā4.6×10−2s−1

b

1.2×10−2s−1

c

2.3×10−2s−1

d

8.4×10−2s−1

answer is C.

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Detailed Solution

k=2.303tlog⁡aa−xkt2.303=log⁡a−log⁡(a−x)∴log⁡(a−x)=log⁡a−kt2.303log⁡(a−x)=log⁡a−k2.303t(Equation of straight line)y = mx + c Slope =−k2.303=−610×60∴k=2.30×10−2s−1
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