Q.
The conversion of vinyl allyl ether to pent-4-enol follows first order kinetics. The following plot is obtained for such a reaction:The rate constant for the reaction is
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a
Ā4.6×10−2s−1
b
1.2×10−2s−1
c
2.3×10−2s−1
d
8.4×10−2s−1
answer is C.
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Detailed Solution
k=2.303tlogaa−xkt2.303=loga−log(a−x)∴log(a−x)=loga−kt2.303log(a−x)=loga−k2.303t(Equation of straight line)y = mx + c Slope =−k2.303=−610×60∴k=2.30×10−2s−1
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