Q.
The coordination number and the oxidation state of the element ‘E’ in the complex [E(en)2(C2O4)]NO2 (where) (en) is ethylene diamane are, respectively,
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a
6 and 3
b
4 and 2
c
4 and 3
d
6 and 2
answer is A.
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Detailed Solution
In the given complex we have two bidentate ligands (i.e en and C2O4 ), so coordination number of E is 6 (2×2+1×2=6) Let the oxidation state of E in complex be x, then [x+(−2)=1] or x−2=1 or x=+3, so its oxidation state is + 3 Thus option (a) is correct.
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