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Q.

The correct acidity order of the following is

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a

(III) > (IV) > (II) > (I)

b

(IV) > (III) > (I) > (II)

c

(III) > (II) > (I) > (IV)

d

(II) > (III) > (IV) > (I)

answer is A.

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Detailed Solution

Carboxylic acid is more acidic than phenol. When an electron releasing group is present in the para position to -COOH group in aromatic carboxylic acid, the acidity is reduced. When Cl atom is present in the para position to -OH group in phenol, it increases its acidity because -Cl  withdraws electron density from the ring and stabilizes the phenoxide ion.
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The correct acidity order of the following is