Q.

The correct acidity order of the following is

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a

III > IV > I > II

b

I > II > III > IV

c

II > III > I > IV

d

I > II > IV > III

answer is D.

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Detailed Solution

In general, acids have greater tendency to lose  H+ compared to alcohols. Out of I and II; I is stronger acid than II due to the presence of CH3+I  effect  which makes the release of proton difficult from the latter. Out of IV and III, III is a stronger acid due to the presence of  Cl−I effect which facilitates the release of proton than by III. Hence the order of I > II > IV>IIII
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