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Q.

The correct bond order of S-O bond in decreasing order is

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a

OSF2>OSCl2>OSBr2

b

OSCl2>OSBr2>OSF2

c

OSF2>OSBr2>OSCl2

d

OSBr2>OSCl2>OSF2

answer is A.

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Detailed Solution

As electronegativity of halogen attached with sulphur increases, sulphur becomes more electron deficient and hence its tendency to get electrons from oxygen through pπ-dπ bonding also increases, i.e., extent of pπ-dπ bonding increases and hence bond order also increases.
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