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Q.

Correct combination regarding these reactions is

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a

I - Gatterman ; II - Gatterman

b

I - Gatterman ; II - Sandmeyer

c

I - Sandmeyer; II - Gatterman

d

I - Sandmeyer; II - Sandmeyer

answer is C.

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Detailed Solution

Benzene diazoniumchloride →HBrCu2Br2C6H5BrBenzene diazoniumchloride →KCNCu2(CN)2C6H5CNSandmeyer’s reaction – Nucleophilic (or) free radical substitutionBenzene diazoniumchloride →Cu/HClC6H5ClBenzene diazoniumchloride →Cu/HBrC6H5BrBenzene diazoniumchloride →Cu/KCNC6H5ClGatterman’s reaction – Nucleophilic substitutionSandmeyer’s reaction gives better yield.

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