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a
C > B > A > D
b
B > C > D > A
c
C > D > B > A
d
D > C > B > A
answer is C.
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Detailed Solution
EWG increases the acidic strength of phenol , nitrophenols are more acidic than phenol-NO2 grp . . . o, p . . . -I, -M . . . . strong EWG-NO2 grp . . . meta . . . -I, only . . . weak EWG∴ ortho and para nitrophenols are more acidic than meta nitrophenol.In ortho nitrophenol due to chelation, proton is less available for donation.Acidic strenngth of C > D > B > Apka of C(7.1) < D(7.2) < B(8.3) < A