The correct decreasing order of reactivity of A, B, C, D towards electrophilic substitution reactions is

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D > C > B > A

C > D > A > B

D > C > A > B

C > D > B > A

answer is D.

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Detailed Solution

When attached to benzenes ring-OH group . . . -I , +M . . . strong EDG-OCH3 group . . . -I, +M . . . . moderate EDG-CHO group . . . -I, -M . . . strong EWG-NO2 group . . . -I, -M . . . very strong EWGThe intermediate in ESR is arenium ionEWG destabilize arenium ionEDG stabilize arenium ion∴Reactivity of C > D > B > A .

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